Spontaneous room temperature reaction of titanium and its alloys with hydrogen during self-shearing reactive milling

• Published in: Chemical engineering journal (Lausanne, Switzerland : 1996) Vol. 485; p. 149673
• Main Authors: Wyrębska, Iwona, Tomczyk, Katarzyna, Siemiaszko, Dariusz, Zasada, Dariusz, Dworecka-Wójcik, Julita, Pęska, Magda, Chulist, Robert, Koter, Stanisław, Polański, Marek
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.04.2024
• Subjects: Hydrogen storage; Reactive milling; Room temperature; Titanium alloys; Titanium hydride; Titanium alloys; Hydrogen storage; Reactive milling; Titanium hydride; Room temperature
• ISSN: 1385-8947; 1873-3212
• DOI: 10.1016/j.cej.2024.149673

[Display omitted] •titanium spontaneously reacts with hydrogen at room temperature.•reaction starts under pressure when the surface oxide layer is broken.•titanium alloys react faster than pure titanium.•stoichiometric TiH2 is formed. Surface wear-activated spontaneous reactions of titanium and its alloys with hydrogen at room temperature are shown in this work. Titanium powder, intensively mixed under hydrogen pressure in a planetary mill, without any grinding media, reacts readily with hydrogen gas with the formation of stoichiometric titanium dihydride. The reaction, once initiated, proceeds spontaneously even without movement of the milling vial with a similar reaction rate. The moment of initiation of the reaction seems to be related to the removal of oxide impurities from the surface of the titanium particles and is strongly correlated with milling velocity. According to thermogravimetric measurements and X-ray diffraction (XRD) phase analysis, titanium is fully converted to TiH2. Titanium alloys were found to react in the same manner. Ti-5553 (β) reacts more easily than grade 5 Ti (Ti-Gd5) (α’), which is more reactive than grade 2 Ti (Ti-Gd2). The titanium alloy particles maintain their shape and coherency after hydrogenation. The method seems to be extremely cost-effective in the synthesis of titanium hydride and also allows the production of hydrogenated alloyed powders in spherical form, which can potentially be applied in the additive manufacturing of titanium foams. The results also show a significant risk of using titanium alloys in a hydrogen atmosphere at room temperature. It seems that after losing the protective oxide layer, parts made of pure titanium or its alloys may undergo catastrophic destruction after losing strength and ductility upon full conversion to hydride.