Photoassisted degradation of rhodamine B by nanoparticles of α-Bi2Mo3O12 prepared by an amorphous complex precursor

• Published in: Materials chemistry and physics Vol. 112; no. 2; pp. 679 - 685
• Main Authors: Martínez-de la Cruz, A., Marcos Villarreal, S.M.G., Torres-Martínez, Leticia M., López Cuéllar, E., Ortiz Méndez, U.
• Format: Journal Article
• Language: English
• Published: 01.12.2008
• ISSN: 0254-0584
• DOI: 10.1016/j.matchemphys.2008.06.035

Nanoparticles of alpha-Bi2Mo3O12 have been synthesized by a method that involves an amorphous complex precursor. The phase formation process, crystal structure and morphology of the synthesized samples were followed by TGA/DTA, XRD, TEM and SEM techniques. The effect of temperature of calcination on the surface area and optical properties of alpha-Bi2Mo3O12 nanoparticles has been also investigated. The photocatalytical activity of alpha-Bi2Mo3O12 nanoparticles was evaluated in the degradation of rhodamine B molecules in aqueous solution under visible light irradiation. The best photocatalyst was selected by evaluating the photocatalytic properties of samples with different calcination temperatures. The kinetic degradation of rhodamine B was adjusted with a first-order reaction with an apparent rate constant k' = 1.36 X 10-2 min-1 and t1/2 = 51 min for the best material obtained. The mineralization degree of the dye to CO2 and H2O was around 56% after 100 h of irradiation.