Fluorination of “brick and mortar” soft-templated graphitic ordered mesoporous carbons for high power lithium-ion battery

Ordered mesoporous carbon-graphitic carbon composites prepared by the "brick and mortar" method were fluorinated using F sub(2) and investigated as cathodes for primary lithium batteries. The resulting materials have a rich array of C-F species, as measured by XPS, which influence conducti...

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Published inJournal of materials chemistry. A, Materials for energy and sustainability Vol. 1; no. 33; pp. 9414 - 9417
Main Authors Fulvio, Pasquale F., Veith, Gabriel M., Adcock, Jamie L., Brown, Suree S., Mayes, Richard T., Wang, Xiqing, Mahurin, Shannon M., Guo, Bingkun, Sun, Xiao-Guang, Puretzky, Alex A., Rouleau, Christopher M., Geohegan, David B., Dai, Sheng
Format Journal Article
LanguageEnglish
Published United States Royal Society of Chemistry 01.01.2013
Subjects
Brick
Carbon
ENERGY STORAGE
Fluorination
Lithium-ion batteries
MATERIALS SCIENCE
Mortars
Sustainability
Voltage
X-ray photoelectron spectroscopy
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Summary:Ordered mesoporous carbon-graphitic carbon composites prepared by the "brick and mortar" method were fluorinated using F sub(2) and investigated as cathodes for primary lithium batteries. The resulting materials have a rich array of C-F species, as measured by XPS, which influence conduction and voltage profiles.
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USDOE Office of Science (SC)
AC05-00OR22725
ISSN:2050-7488
2050-7496
DOI:10.1039/c3ta10710h