CO2 activation by manganese pincer complexes through different modes of metal–ligand cooperation (Dedicated to Prof. Robin Perutz on the occasion of his 70th Birthday.)

We report here the activation of CO2 using two Mn-PNN pincer complexes that can exhibit different modes of metal–ligand cooperation amido/amino mode that involves [1,2]-activation of CO2 and dearomatization/aromatization mode that involves [1,3]-activation of CO2. We also compare their catalytic act...

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Bibliographic Details
Published inDalton transactions : an international journal of inorganic chemistry Vol. 48; no. 39; pp. 14580 - 14584
Main Authors Kumar, Amit, Daw, Prosenjit, Espinosa-Jalapa, Noel Angel, Leitus, Gregory, Shimon, Linda J W, Ben-David, Yehoshoa, Milstein, David
Format Journal Article
LanguageEnglish
Published Cambridge Royal Society of Chemistry 2019
Subjects
Activation
Carbon dioxide
Catalytic activity
Cooperation
Crystallography
Ligands
Manganese
NMR
Nuclear magnetic resonance
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Summary:We report here the activation of CO2 using two Mn-PNN pincer complexes that can exhibit different modes of metal–ligand cooperation amido/amino mode that involves [1,2]-activation of CO2 and dearomatization/aromatization mode that involves [1,3]-activation of CO2. We also compare their catalytic activity for CO2 hydrogenation.
ISSN:1477-9226
1477-9234
DOI:10.1039/c9dt03088c