Reversible hydrogen storage system of 3NaBH4-0.5ScF3-0.5YF3: The synergistic effect of ScF3 and YF3

• Published in: Journal of alloys and compounds Vol. 791; pp. 1270 - 1276
• Main Authors: Huang, Tianping, Zou, Jianxin, Zhao, Ning, Zeng, Xiaoqin, Ding, Wenjiang
• Format: Journal Article
• Language: English
• Published: Lausanne Elsevier B.V 30.06.2019; Elsevier BV
• Subjects: Ball milling; Dehydrogenation; Desorption; Fluorides; Hydrogen; Hydrogen storage; Metal fluorides; NaBH4; Rare earth elements; Reversible hydrogen storage; ScF3; Substitution reactions; Synergistic effect; Transition metals; YF3; Reversible hydrogen storage; ScF3; NaBH4; YF3
• ISSN: 0925-8388; 1873-4669
• DOI: 10.1016/j.jallcom.2019.02.306

A new reversible hydrogen storage system, 3NaBH4-0.5ScF3-0.5YF3, was synthesized by using the ball-milling method. It is shown that no reaction occurs during the ball-milling process. The hydrogen desorption process of the ball-milled composite can be divided into three consecutive steps: (i) An initial stage from room temperature to 320 °C with about 0.42 wt% of hydrogen released, that can be ascribed to the substitution of H− by F− in NaBH4; (ii) The second stage starts from 320 °C to 450 °C, releasing about 1.06 wt% of hydrogen; (iii) The final stage ranges from 450 °C to 480 °C, with 2.58 wt% of hydrogen released. The total yield of hydrogen reaches 4.06 wt% at 480 °C. The completely dehydrogenated products of the 3NaBH4-0.5ScF3-0.5YF3 composite can absorb 2.15 wt% of hydrogen at 380 °C in 6.5 h, which shows greatly enhanced reversibility when compared with sole ScF3 addition. It should be noted that one of the destabilizers ScF3 was also regenerated besides NaBH4 in the rehydrogenated products. Based on the XRD and FTIR analyses, the synergistic effects of 3d transition metal fluoride ScF3 and rare earth metal fluoride YF3 on the hydrogen desorption and absorption performance of NaBH4 were discussed. •A new reversible hydrogen storage system 3NaBH4-0.5ScF3-0.5YF3 was proposed.•Three consecutive step hydrogen desorption can be observed.•3NaBH4-0.5ScF3-0.5YF3 shows better reversibility than 3NaBH4-ScF3.•With the help of YF3, NaBH4 and ScF3 are regenerated after hydrogen absorption.