Laser stimulation of low-temperature dissociative recombination of electrons and oxygen molecular ions

• Published in: Russian journal of physical chemistry. B Vol. 3; no. 2; pp. 195 - 210
• Main Authors: Adamson, S. O., Buenker, R. J., Golubkov, G. V., Golubkov, M. G., Dement’ev, A. I.
• Format: Journal Article
• Language: English
• Published: Moscow Nauka/Interperiodica 01.04.2009
• Subjects: Chemistry; Chemistry and Materials Science; Effect of External Factors on Physicochemical Transformations; Physical Chemistry; Rydberg State; Incident Electron; Dissociative Recombination; Potential Curve; Potential Curf
• ISSN: 1990-7931; 1990-7923
• DOI: 10.1134/S1990793109020055

A theory of dissociative recombination of slow electrons and molecular ions in a strong monochromatic light field is developed. The theory takes into account interference between various reaction channels and is constructed in a rigid basis adiabatic with respect to rotation (the approximation of a fixed molecular axis). The mathematical apparatus of the theory is based on the stationary formalism of the matrix of radiation collisions, whose poles correspond to “quasi-energy” states of a composite system. Along with transitions into dissociative configurations, field-induced nonadiabatic transitions into bound intermediate states of valence (non-Rydberg) configurations are considered. As a particular application of the theory, the e − + O 2 + ( 2 Π g ) → reaction is analyzed. A study of this reaction requires detailed information about the potential curves of the states participating in it with taking into account the external electromagnetic field ( l and s are the electronic angular momenta and reaction product spins). For this purpose, the general problem is divided into three stages. At the first stage, the theoretical approach is formulated, and at the second stage, the corresponding potential curves are calculated and the main reaction mechanisms are determined. The third stage should include calculations of the total and differential cross sections. This work is concerned with the first two stages; that is, the adiabatic potential curves of the singlet and triplet dissociative states of the O 2 ** oxygen molecule are calculated, a classification of all possible transition types is given, and reaction mechanisms in the presence of monochromatic laser radiation are determined. The frequency regions of external radiation in which these mechanisms are most effective are found.