AN EXTENDED NICKEL DITHIOLENE COMPLEX - MOLECULAR ELECTRONIC MATERIALS BASED ON PLANAR BIMETALLIC SUBUNITS

The species Ni2C2S4{S2C2S2C2(CO2Me)2}2, a new type of molecular electronic component, forms in good yield via two oxidation steps from [Ni{S2C2S2C2(CO2Me)2}2]2-; the extended planar structure of the intermediate [Ni2C2S4{S2C2S2(CO2Me)2}2]2- was confirmed crystallographically.

Saved in:
Bibliographic Details
Published inJournal of the Chemical Society. Chemical communications no. 7; pp. 821 - 822
Main Authors YANG, XG, DOXSEE, DD, RAUCHFUSS, TB, WILSON
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 1994
Royal Society of Chemistry
Subjects
Chemistry
Chemistry, Multidisciplinary
Condensed matter: structure, mechanical and thermal properties
Coordination compounds
Exact sciences and technology
Inorganic chemistry and origins of life
Inorganic compounds
Metal complexes
Physical Sciences
Physics
Preparations and properties
Science & Technology
Structure of solids and liquids; crystallography
Structure of specific crystalline solids
1,3-DITHIOLE-2-THIONE-4,5-DITHIOLATE
CHEMISTRY
METAL
CRYSTAL
ACCESS
Ester
Nickel Complexes
Molecular structure
Thiolate
Dinuclear complex
Organic ligand
Transition metal Complexes
Experimental study
X ray diffraction
Ethylenic compound
Magnetic properties
Crystalline structure
Online AccessGet full text

Cover

More Information
Summary:The species Ni2C2S4{S2C2S2C2(CO2Me)2}2, a new type of molecular electronic component, forms in good yield via two oxidation steps from [Ni{S2C2S2C2(CO2Me)2}2]2-; the extended planar structure of the intermediate [Ni2C2S4{S2C2S2(CO2Me)2}2]2- was confirmed crystallographically.
ISSN:0022-4936
DOI:10.1039/c39940000821