ALKYLIDENECARBENE INSERTIONS INTO AROMATIC C-H BONDS IN SOLUTION

Reaction of sodium toluene-p-sulfinate with (Ar)2(OH)CC=Cfl(Ph)(OSO2CF3) results in substituted indenes via alkylidenecarbene aromatic C-H bond insertions.

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Bibliographic Details
Published inJournal of the Chemical Society. Chemical communications no. 24; pp. 1800 - 1801
Main Authors TYKWINSKI, RR, WHITEFORD, JA, STANG, PJ
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 1993
Royal Society of Chemistry
Subjects
Alicyclic compounds
Alicyclic compounds, terpenoids, prostaglandins, steroids
Aliphatic, non-condensed and condensed benzenic, and alicyclic compounds
Chemistry
Chemistry, Multidisciplinary
Condensed matter: structure, mechanical and thermal properties
Exact sciences and technology
Organic chemistry
Organic compounds
Physical Sciences
Physics
Preparations and properties
Science & Technology
Structure of solids and liquids; crystallography
Structure of specific crystalline solids
THERMAL REARRANGEMENTS
CARBENES
METHYLENECARBENES
CYCLIZATION
METHYLENEKETENES
Iodine III Organic compounds
Sulfinate
Hydroxysulfone
Cyclization
Molecular structure
Bicyclic compound
Aromatic compound
Experimental study
X ray diffraction
Organic compounds
Crystalline structure
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Summary:Reaction of sodium toluene-p-sulfinate with (Ar)2(OH)CC=Cfl(Ph)(OSO2CF3) results in substituted indenes via alkylidenecarbene aromatic C-H bond insertions.
ISSN:0022-4936
DOI:10.1039/c39930001800