A first example of a reaction under viscous conditions: oxidation of solid benzoins with manganese dioxide

A new, general, and efficient technique for the reaction of solid substrates under viscous conditions with shaking at room temperature is described, which can overcome some of the problems existing in common solvent-free reactions solids as the starting materials. In this manuscript we present as a...

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Bibliographic Details
Published inMonatshefte für Chemie Vol. 139; no. 6; pp. 609 - 611
Main Authors Lou, Ji-Dong, Lu, Xiu L., Marrogi, Aizen J., Li, Feng, Gao, Chun-Ling, Yu, Xiaoping
Format Journal Article
LanguageEnglish
Published Vienna Springer-Verlag 01.06.2008
Springer Nature
Subjects
Analytical Chemistry
Chemistry
Chemistry and Materials Science
Chemistry, Multidisciplinary
Chemistry/Food Science
Inorganic Chemistry
Organic Chemistry
Physical Chemistry
Physical Sciences
Science & Technology
Theoretical and Computational Chemistry
Viscous conditions; Solid substrate; Solvent-free reactions; Oxidation; Solid benzoins
oxidation
viscous conditions
solid benzoins
solid substrate
solvent-free reactions
BENZILS
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Summary:A new, general, and efficient technique for the reaction of solid substrates under viscous conditions with shaking at room temperature is described, which can overcome some of the problems existing in common solvent-free reactions solids as the starting materials. In this manuscript we present as a first example of this method the oxidation of solid benzoins into the corresponding benzils using an environmentally friendly and inexpensive oxidant, manganese dioxide.
ISSN:0026-9247
1434-4475
DOI:10.1007/s00706-007-0800-5