Spectroscopic and theoretical studies on [Co(η-C 5 Me 5 )Et(PMe 2 Ph)] + : evidence for dynamic inversion of chirality at cobalt

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Bibliographic Details
Published inJournal of the Chemical Society. Chemical communications no. 13; pp. 1005 - 1006
Main Authors Cracknell, Robert B., Orpen, A. Guy, Spencer, J. L.
Format Journal Article
LanguageEnglish
Published Cambridge Royal Society of Chemistry 1986
Subjects
Chemistry
Exact sciences and technology
Kinetics and mechanisms
Organic chemistry
Reactivity and mechanisms
Cationic complex
Cobalt Complexes
Chemical solution
Chemical rearrangement
Internal rotation
Organic ligand
Theoretical study
Transition metal Complexes
Exchange reaction
Experimental study
Hydrido complex
Cobalt Organic compounds
Chirality
Complexes Mixed
Extended Hueckel method
Thermodynamic properties
NMR spectrum
Conformation
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ISSN:0022-4936
DOI:10.1039/C39860001005