Investigation on Claisen rearrangement of allyl phenyl ethers in near-critical water
Catalyst-free Clasien rearrangement of allyl phenyl ethers were investigated in near-critical water. The effects on the reaction in near-critical water and conventional conditions were compared. The results demonstrate that near-critical water could greatly accelerate the Claisen rearrangement of al...
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Published in | Research on chemical intermediates Vol. 41; no. 6; pp. 3299 - 3305 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
Dordrecht
Springer Netherlands
01.06.2015
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Subjects | |
Online Access | Get full text |
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Summary: | Catalyst-free Clasien rearrangement of allyl phenyl ethers were investigated in near-critical water. The effects on the reaction in near-critical water and conventional conditions were compared. The results demonstrate that near-critical water could greatly accelerate the Claisen rearrangement of allyl phenyl ethers. This process is simple, fast, efficient and environmentally benign. |
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ISSN: | 0922-6168 1568-5675 |
DOI: | 10.1007/s11164-013-1433-4 |