Investigation on Claisen rearrangement of allyl phenyl ethers in near-critical water

Catalyst-free Clasien rearrangement of allyl phenyl ethers were investigated in near-critical water. The effects on the reaction in near-critical water and conventional conditions were compared. The results demonstrate that near-critical water could greatly accelerate the Claisen rearrangement of al...

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Bibliographic Details
Published inResearch on chemical intermediates Vol. 41; no. 6; pp. 3299 - 3305
Main Authors Xiao, Shangyou, He, Yi, Xu, Guang, Liu, Qi
Format Journal Article
LanguageEnglish
Published Dordrecht Springer Netherlands 01.06.2015
Subjects
Catalysis
Chemistry
Chemistry and Materials Science
Inorganic Chemistry
Physical Chemistry
Near-critical water
Clasien rearrangement
Allyl phenyl ethers
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Summary:Catalyst-free Clasien rearrangement of allyl phenyl ethers were investigated in near-critical water. The effects on the reaction in near-critical water and conventional conditions were compared. The results demonstrate that near-critical water could greatly accelerate the Claisen rearrangement of allyl phenyl ethers. This process is simple, fast, efficient and environmentally benign.
ISSN:0922-6168
1568-5675
DOI:10.1007/s11164-013-1433-4