Electrochemical Capacitance of Activated Carbons Regenerated using Thermal and Chemical Activation

• Published in: Journal of Electrochemical Science and Technology Vol. 12; no. 3; pp. 339 - 345
• Main Authors: Park, Jung Eun, Lee, Gi Bbum, Hwang, Sang Youp
• Format: Journal Article
• Language: English
• Published: 01.08.2021
• ISSN: 2093-8551; 2288-9221
• DOI: 10.33961/jecst.2020.01683

Spent activated carbons (SACs) collected from a water treatment plant were regenerated and then adopted as electrochemical material in capacitors. The SACs used in this study were regenerated via two steps, namely thermal and chemical activation. However, during the activation process, the adsorbates were converted into ashes, which caused pore blockage and decreased specific surface area. The regenerated SACs were washed with acid solutions with different levels of acidity (strong: HCl, mild: H3PO4, and weak: H2O2) to remove the ashes. The regenerated SACs washed with HCl exhibited the highest specific surface area, although their capacitance was not the highest. Conversely, the specific surface area of regenerated SACs washed using H3PO4 was slightly lower than that of HCl, but exhibited higher capacitance and electrochemical stability. Although the strong acid removed the generated ashes in the pores efficiently, it could adversely affect their structural stability, which would lead to lower capacitance.