Kinetic theory and irreversible thermodynamics of dense fluids subject to an external field

A formal theory of dense fluids subject to an external electric field is developed as an extension of the kinetic theory of dense fluids reported previously. The present formulation also refines and modifies the previous theory wherever deemed necessary and especially in the part related to the reno...

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Bibliographic Details
Published inThe Journal of chemical physics Vol. 87; no. 2; pp. 1220 - 1237
Main Author Eu, Byung Chan
Format Journal Article
LanguageEnglish
Published Woodbury, NY American Institute of Physics 15.07.1987
Subjects
Chemistry
Electrochemistry
Exact sciences and technology
General and physical chemistry
Properties of electrolytes: conductivity
Theoretical study
Gibbs free energy
Electric field
Simulation
Electrolyte solution
Thermodynamic properties
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Summary:A formal theory of dense fluids subject to an external electric field is developed as an extension of the kinetic theory of dense fluids reported previously. The present formulation also refines and modifies the previous theory wherever deemed necessary and especially in the part related to the renormalization. The extended Gibbs relation and a theory of irreversible thermodynamics are developed. A generalized Kirkwood integral equation for correlation functions and a generalized equation for local nonequilibrium chemical potentials are also derived for nonequilibrium mixtures.
ISSN:0021-9606
1089-7690
DOI:10.1063/1.453303