Coordination supramolecular structures

Supramolecular coordination ensembles with d -metal ions directly incorporated into their structures are the subject of the present review. Diversity of such structures considerably exceeds that of purely organic supramolecules due to inclusion of additional polyvalent metal atoms (totally sixty) wi...

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Bibliographic Details
Published inRussian journal of general chemistry Vol. 79; no. 12; pp. 2711 - 2722
Main Authors Alekseev, Yu. E., Garnovskii, A. D.
Format Journal Article
LanguageEnglish
Published Dordrecht SP MAIK Nauka/Interperiodica 01.12.2009
Subjects
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Coord
Coordination Polymer
General Chemistry
Supramolecular Chemistry
Comprehensive Coordination Chemistry
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Summary:Supramolecular coordination ensembles with d -metal ions directly incorporated into their structures are the subject of the present review. Diversity of such structures considerably exceeds that of purely organic supramolecules due to inclusion of additional polyvalent metal atoms (totally sixty) with diverse coordination geometry. Such metal-containing constructions are generated by self-assembling and (or) by templating, as 2D and 3D geometric figures (polygons and polyhedra) and “furniture” constructions (ladders, racks, grids) together with helicates, interwoven species and metallodendrimers as combinations of 1D coordination compounds. Besides, is presented a numerous of coordination polymers and supramolecular crystal lattices as infinite structures.
ISSN:1070-3632
1608-3350
DOI:10.1134/S1070363209120305