Radical polymerization of acrylonitrile under the action of catalytic systems based on zero-valent copper

Specific features of the (co)polymerization of acrylonitrile in the presence of a catalytic system based on zero-valent copper and 2,2-bipyridyl in various solvents was studied. It is shown that these systems can be successfully used in the presence of halogen-containing initiators to obtain homo- a...

Full description

Saved in:
Bibliographic Details
Published inRussian journal of applied chemistry Vol. 88; no. 8; pp. 1275 - 1281
Main Authors Grishin, I. D., Kurochkina, D. Yu, Grishin, D. F.
Format Journal Article
LanguageEnglish
Published Moscow Pleiades Publishing 01.08.2015
Subjects
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Industrial Chemistry/Chemical Engineering
Macromolecular Compounds and Polymeric Materials
Itaconic Acid
Acrylonitrile
Methyl Acrylate
Radical Polymerization
Bipy
Online AccessGet full text

Cover

More Information
Summary:Specific features of the (co)polymerization of acrylonitrile in the presence of a catalytic system based on zero-valent copper and 2,2-bipyridyl in various solvents was studied. It is shown that these systems can be successfully used in the presence of halogen-containing initiators to obtain homo- and copolymers of acrylonitrile with dimethyl itaconate and methyl acrylate in the controlled mode. It was found that introduction of comonomers (methyl acrylate and dimethyl itaconate) in low concentrations has no effect on parameters of the acrylonitrile polymerization process, but strongly affects some properties and characteristics of samples being synthesized.
ISSN:1070-4272
1608-3296
DOI:10.1134/S107042721508008X