A NOVEL SYNTHESIS OF (OXODIMETHYLENEMETHANE)-PALLADIUM AND (OXODIMETHYLENEMETHANE)-PLATINUM COMPLEXES

Treatment of pi-allyl-palladium and -platinum complexes bearing a methoxymethoxy group at the 2-position with base give the corresponding oxodimethylenemethane complexes, in contrast to the formation of 2-hydroxy-substituted pi-allyl complexes via acidic hydrolysis.

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Bibliographic Details
Published inJournal of the Chemical Society. Chemical communications no. 12; pp. 1039 - 1040
Main Authors OHSUKA, A, FUJIMORI, T, HIRAO, T, KUROSAWA, H, IKEDA
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 1993
Royal Society of Chemistry
Subjects
Chemistry
Chemistry, Multidisciplinary
Coordination compounds
Exact sciences and technology
Inorganic chemistry and origins of life
Physical Sciences
Preparations and properties
Science & Technology
CHEMISTRY
PALLADIUM
Platinum Complexes
Tertiary phosphine
Palladium Complexes
Preparation
Organic ligand
Platinoid Complexes
Transition metal Complexes
NMR spectrum
Physical properties
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Summary:Treatment of pi-allyl-palladium and -platinum complexes bearing a methoxymethoxy group at the 2-position with base give the corresponding oxodimethylenemethane complexes, in contrast to the formation of 2-hydroxy-substituted pi-allyl complexes via acidic hydrolysis.
ISSN:0022-4936
DOI:10.1039/c39930001039