HYDROFORMYLATION OF OCT-1-ENE WITH EXTREMELY HIGH-RATES USING RHODIUM CATALYSTS CONTAINING BULKY PHOSPHITES

A rhodium complex containing tris(o-tert-butyl-p-methylphenyl) phosphite as a ligand catalyses the hydroformylation of oct-1-ene with good selectivity and extremely high rates; the rate constant, which is pseudo first-order in [H-2] and 1/[CO], shows that the reaction of hydrogen is the rate determi...

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Bibliographic Details
Published inJournal of the Chemical Society. Chemical communications no. 16; pp. 1096 - 1097
Main Authors VANROOY, A, ORIJ, EN, KAMER, PCJ, VANDENAARDWEG, F, VANLEEUWEN, PWNM
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 1991
Royal Society of Chemistry
Subjects
Chemistry
Chemistry, Multidisciplinary
Exact sciences and technology
Kinetics and mechanisms
Organic chemistry
Physical Sciences
Reactivity and mechanisms
Science & Technology
OLEFINS
MECHANISM
LIGANDS
KINETICS
LOW-PRESSURE
Organic phosphite
Rhodium Carbonyl Complexes
Catalytic reaction
Hydrocarbon
Aliphatic compound
Hydrogen
Organic ligand
Pressure
Medium effect
Hydroformylation
Carbon monoxide
Rate constant
Ethylenic compound
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Summary:A rhodium complex containing tris(o-tert-butyl-p-methylphenyl) phosphite as a ligand catalyses the hydroformylation of oct-1-ene with good selectivity and extremely high rates; the rate constant, which is pseudo first-order in [H-2] and 1/[CO], shows that the reaction of hydrogen is the rate determining step.
ISSN:0022-4936
DOI:10.1039/c39910001096