Photostimulated transformations in nanosized MoO3 films

• Published in: Russian Journal of Physical Chemistry A Vol. 87; no. 12; pp. 2063 - 2067
• Main Authors: Surovoi, E. P., Borisova, N. V., Bugerko, L. N., Surovaya, V. E., Ramazanova, G. O.
• Format: Journal Article
• Language: English
• Published: Boston Springer US 01.12.2013
• Subjects: Chemistry; Chemistry and Materials Science; Physical Chemistry; Physical Chemistry of Nanoclusters and Nanomaterials; photochemical transformations; mechanism; nanosized molybdenum(VI) oxide films

Irradiation of MoO 3 films (with a thickness d = 5–54 nm) with light (λ = 320 nm, I = (1.5–7) × 10 15 quantum cm −2 s −1 ) led to the formation of an absorption band at λ = 870 nm along with the shift of the edge of the absorption band to the short-wave region of the spectrum. Further irradiation of...