Continuous synthesis process of methanol at low temperature from syngas using alcohol promoters

A continuous process for low-temperature methanol synthesis from CO/CO 2/H 2 based on the promoting effect of alcohol solvent has been developed. 2-butanol, acting as a promoter, with the aid of Cu/ZnO solid catalyst, realized the high efficient synthesis of methanol with one-pass methanol yield of...

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Bibliographic Details
Published inCatalysis communications Vol. 2; no. 6; pp. 213 - 217
Main Authors Tsubaki, Noritatsu, Zeng, Jianqing, Yoneyama, Yoshiharu, Fujimoto, Kaoru
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.09.2001
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Summary:A continuous process for low-temperature methanol synthesis from CO/CO 2/H 2 based on the promoting effect of alcohol solvent has been developed. 2-butanol, acting as a promoter, with the aid of Cu/ZnO solid catalyst, realized the high efficient synthesis of methanol with one-pass methanol yield of 47.0% and methanol selectivity of 98.9% at temperature as low as 443 K and 50 bar, which can be a very promising method for methanol production at low temperature.
ISSN:1566-7367
1873-3905
DOI:10.1016/S1566-7367(01)00039-5