Synthetic Applications (I) of the Tandem [2,3]-Wittig-Anionic Oxy-Cope Rearrangement: Stereoselective Disubstituted Tetrahydropyran Synthesis by Electrophile Initiated Cyclisation
Reduction of the δ,ε-unsaturated aldehydes produced by tandem [2,3]-Wittig-anionic oxy-Cope rearrangement followed by stereoselective electrophilic cyclisation and reductive removal of the electrophile leads to single diastereoisomers of tetrahydropyrans. © 1997 Elsevier Science Ltd.
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| Published in | Tetrahedron letters Vol. 38; no. 36; pp. 6449 - 6452 |
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| Main Authors | , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier Ltd
01.09.1997
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| Online Access | Get full text |
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| Summary: | Reduction of the δ,ε-unsaturated aldehydes produced by tandem [2,3]-Wittig-anionic oxy-Cope rearrangement followed by stereoselective electrophilic cyclisation and reductive removal of the electrophile leads to single diastereoisomers of tetrahydropyrans. © 1997 Elsevier Science Ltd. |
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| ISSN: | 0040-4039 1873-3581 |
| DOI: | 10.1016/S0040-4039(97)01474-3 |