Synthesis and nitration of 3-R-4-(2,2,2-trinitroethyl)aminofuroxans

Simple methods for the synthesis of 3-R-4-(2,2,2-trinitroethyl)aminofuroxans were developed based on the Mannich reaction of N , N ′-bis(3-R-furoxan-4-yl)methylenediamines with trinitromethane or 3-R-4-aminofuroxans with trinitroethanol or with CH 2 O and trinitromethane. The Mannich bases obtained...

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Bibliographic Details
Published inRussian chemical bulletin Vol. 61; no. 8; pp. 1575 - 1581
Main Authors Epishina, M. A., Finogenov, A. O., Kulikov, A. S., Makhova, N. N., Anan’ev, I. V., Tartakovsky, V. A.
Format Journal Article
LanguageEnglish
Published Boston Springer US 01.08.2012
Subjects
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
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Inorganic Chemistry
Organic Chemistry
bis(3-R-furoxan-4-yl)methylenediamines
3-R-4-aminofuroxans
3-R-4-(2,2,2-trinitroethyl)amino(nitramino)furoxans
Mannich reaction
nitration
X-ray analysis
,
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Summary:Simple methods for the synthesis of 3-R-4-(2,2,2-trinitroethyl)aminofuroxans were developed based on the Mannich reaction of N , N ′-bis(3-R-furoxan-4-yl)methylenediamines with trinitromethane or 3-R-4-aminofuroxans with trinitroethanol or with CH 2 O and trinitromethane. The Mannich bases obtained were studied in the nitration reaction, which showed their ability to form nitramines depending on substituents on the furoxan ring.
ISSN:1066-5285
1573-9171
DOI:10.1007/s11172-012-0209-0