Chair-chair interconversion in some highly substituted 1,2,4-trioxanes and 1,3-dioxanes. A dynamic NMR study of a striking effect of skeletal substitution

• Published in: J. Chem. Soc., Perkin Trans. 2 no. 10; pp. 1927 - 1929
• Main Authors: ANDERSON, J. E, BLOODWORTH, A. J, ANEELA SHAH
• Format: Journal Article
• Language: English
• Published: Cambridge Royal Society of Chemistry 1993
• Subjects: Atomic and molecular physics; Barrier heights (internal rotation, inversion, rotational isomerism, conformational dynamics); Calculations and mathematical techniques in atomic and molecular physics (excluding electron correlation calculations); Conformation (statistics and dynamics); Electronic structure of atoms, molecules and their ions: theory; Exact sciences and technology; Macromolecules and polymer molecules; Molecular properties and interactions with photons; Nuclear resonance and relaxation; Physics; Statistical model calculations (including Thomas-Fermi and Thomas-Fermi-Dirac models); Studies of special atoms, molecules and their ions; clusters; Substituent effect; Molecular structure; Bond angle; Theoretical study; Experimental study; Conformational changes; Bond lengths; Hydrogen 1; Temperature effects; Heterocyclic oxygen compounds; Force field method; NMR spectra; Organic compounds
• ISSN: 0300-9580; 2050-8239; 1364-5471
• DOI: 10.1039/P29930001927