Acid-catalyzed reactions of thiocyanates with camphene

The reactions of thiocyanates with camphene catalyzed by the heteropoly acids H 3 PW 12 O 40 and H 4 SiW 12 O 40 were studied. The optimal reaction conditions were found, and the formation of N-substituted thiocarbamates in comparatively high yields was established. It was shown that the heteropoly...

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Bibliographic Details
Published inKinetics and catalysis Vol. 49; no. 3; pp. 391 - 394
Main Authors Arkhipova, A. V., Malkova, K. V., Sokolova, T. N., Kartashov, V. R.
Format Journal Article
LanguageEnglish
Published Dordrecht SP MAIK Nauka/Interperiodica 01.05.2008
Subjects
Catalysis
Chemistry
Chemistry and Materials Science
Physical Chemistry
Terpene
Camphene
Optimal Reaction Condition
Heteropoly Acid
Thiocyanate
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Summary:The reactions of thiocyanates with camphene catalyzed by the heteropoly acids H 3 PW 12 O 40 and H 4 SiW 12 O 40 were studied. The optimal reaction conditions were found, and the formation of N-substituted thiocarbamates in comparatively high yields was established. It was shown that the heteropoly acids exhibit a higher catalytic activity than sulfuric acid.
ISSN:0023-1584
1608-3210
DOI:10.1134/S0023158408030117