Feather-like NiCo2O4 self-assemble from porous nanowires as binder-free electrodes for low charge transfer resistance

• Published in: Frontiers of materials science Vol. 14; no. 4; pp. 450 - 458
• Main Authors: Han, Dandan, Wei, Jinhe, Wang, Shanshan, Pan, Yifan, Xue, Junli, Wei, Yen
• Format: Journal Article
• Language: English
• Published: Beijing Higher Education Press 01.12.2020
• Subjects: Chemistry and Materials Science; Materials Science; Research Article; binder-free electrode; charge transfer resistance; feather-like NiCo; O; supercapacitor
• ISSN: 2095-025X; 2095-0268
• DOI: 10.1007/s11706-020-0528-2

The unique feather-like arrays composing of ultrathin secondary nanowires are fabricated on nickel foam (NF) through a facile hydrothermal strategy. Thus, the enhancement of electrochemical properties especially the low charge transfer resistance strongly depends on more active sites and porosity of the morphology. Benefiting from the unique structure, the optimized NiCo 2 O 4 electrode delivers a significantly lower charge transfer resistance of 0.32 Ω and a high specific capacitance of 450 F·g −1 at 0.5 A·g −1 , as well as a superior cycling stability of 139.6% capacitance retention. The improvement of the electrochemical energy storage property proves the potential of the fabrication of various binary metal oxide electrodes for applications in the electrochemical energy field.