Synthesis of acetic-methacrylic acid diesters of norbornane-2,5-diol and (2-hydroxynorborn-5-yl)methanol

Reaction of addition of acrylic acids to 5-acetoxy- and 5-acetoxymethylnorborn-2-ene in the presence of a BF 3 ·O(C 2 H 5 ) 2 catalyst was studied in order to synthesize mixed acetic-acrylic acid diesters of norbornane-2,5-diol and (2-hydroxynorborn-5-yl)methanol, which are new monomers for synthese...

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Bibliographic Details
Published inRussian journal of applied chemistry Vol. 83; no. 11; pp. 1978 - 1981
Main Authors Mamedov, M. K., Kadyrly, V. S.
Format Journal Article
LanguageEnglish
Published Dordrecht SP MAIK Nauka/Interperiodica 01.11.2010
Subjects
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Industrial Chemistry/Chemical Engineering
Organic Synthesis and Industrial Organic Chemistry
Diol
Reaction Duration
Acrylic Acid
Diester
Norbornane
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Summary:Reaction of addition of acrylic acids to 5-acetoxy- and 5-acetoxymethylnorborn-2-ene in the presence of a BF 3 ·O(C 2 H 5 ) 2 catalyst was studied in order to synthesize mixed acetic-acrylic acid diesters of norbornane-2,5-diol and (2-hydroxynorborn-5-yl)methanol, which are new monomers for syntheses of polymers.
ISSN:1070-4272
1608-3296
DOI:10.1134/S1070427210110169