ENANTIOSELECTIVE AEROBIC EPOXIDATION OF ACYCLIC SIMPLE OLEFINS CATALYZED BY THE OPTICALLY-ACTIVE BETA-KETOIMINATO MANGANESE(III) COMPLEX

Enantioselective aerobic epoxidation of acyclic cis-olefins into the corresponding optically active epoxides was carried out with good-to-high enantioselectivities by using a new class of optically active beta-ketoiminato manganese(III) complex catalyst, N,N'-ethylenebis(alpha-mesitoyl-beta-ket...

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Bibliographic Details
Published inChemistry letters no. 7; pp. 1259 - 1262
Main Authors NAGATA, T, IMAGAWA, K, YAMADA, T, MUKAIYAMA, T
Format Journal Article
LanguageEnglish
Published TOKYO Chemical Soc Japan 01.07.1994
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
UNFUNCTIONALIZED OLEFINS
OXIDATION
ASYMMETRIC EPOXIDATION
ALKENES
PORPHYRINS
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Summary:Enantioselective aerobic epoxidation of acyclic cis-olefins into the corresponding optically active epoxides was carried out with good-to-high enantioselectivities by using a new class of optically active beta-ketoiminato manganese(III) complex catalyst, N,N'-ethylenebis(alpha-mesitoyl-beta-ketoiminato)manganese(III) chloride. The key intermediate of the present epoxidation is also discussed.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.1994.1259