E. grandis as a Biocarbons Precursor for Supercapacitor Electrode Application

• Published in: Waste and biomass valorization Vol. 5; no. 2; pp. 305 - 313
• Main Authors: Cuña, Andrés, Tancredi, Nestor, Bussi, Juan, Deiana, Ana Cristina, Sardella, Maria Fabiana, Barranco, Violeta, Rojo, José M.
• Format: Journal Article
• Language: English
• Published: Dordrecht Springer Netherlands 01.04.2014
• Subjects: Engineering; Environment; Environmental Engineering/Biotechnology; Industrial Pollution Prevention; Original Paper; Renewable and Green Energy; Waste Management/Waste Technology; Supercapacitors; Biocarbons; wood; Activated carbons; Wood residues; Energy storage
• ISSN: 1877-2641; 1877-265X
• DOI: 10.1007/s12649-013-9257-4

Wood residues are ordinary wastes in the forestry industry and their valorization is an important issue. Eucalyptus grandis wood dust was chosen as a model wood residue and biocarbons (BCs) and activated BCs were prepared from it and studied as active materials for supercapacitor electrodes. Several ordinary activation methods were used and microporous activated BCs with specific surface areas up to 900 m 2  g −1 , and different content of oxygenated surface groups were obtained. The preparation or activation temperature is the parameter that mainly affects the electrical conductivity. For temperatures above 700 °C, the samples reach an electrical conductivity as high as 1 S cm −1 . The specific capacitance of the activated BCs reaches values up to 203 F g −1 in acidic electrolyte. The highest specific capacitance is obtained when chemical activation with ZnCl 2 at 900 °C followed by chemical oxidation with nitric acid is used. BCs activated with ZnCl 2 at 900 °C and CO 2 at 800 °C displayed good rate capability and the maximum power density. Activation with ZnCl 2 at 900 °C also leads to BCs with the maximum energy density. These results show that E. grandis wood dust is a promising low cost and environmental friendly precursor for biocarbon electrodes.