HIGH-PRESSURE DIELS-ALDER REACTION OF [60]FULLERENE WITH SEVERAL TROPONES - CHARACTERIZATION OF THE 1/1-CYCLOADDUCTS

The high-pressure Diels-Alder reaction of fullerite with tropone and several of its derivatives under 300 MPa gave 1:1-[4 + 2] cycloadducts of C-60 in good yields. Their H-1 and C-13 NMR spectra were consistent with the structures depicted. These compounds quantitatively regenerate starting material...

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Bibliographic Details
Published inJ. Chem. Soc., Perkin Trans. 1 no. 11; pp. 1433 - 1437
Main Authors TAKESHITA, H, LIU, JF, KATO, N, MORI, A, ISOBE, R
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 1994
Royal Society of Chemistry
Subjects
Alicyclic compounds
Alicyclic compounds, terpenoids, prostaglandins, steroids
Chemistry
Chemistry, Organic
Exact sciences and technology
Organic chemistry
Physical Sciences
Preparations and properties
Science & Technology
BUCKMINSTERFULLERENE
C-60
ADDUCT
C60
BENZYNE
Polyhedral molecule
Carbon Molecules
Fullerenes
Diels Alder addition
Atomic cluster
Ketone
Monocyclic compound
High pressure
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Summary:The high-pressure Diels-Alder reaction of fullerite with tropone and several of its derivatives under 300 MPa gave 1:1-[4 + 2] cycloadducts of C-60 in good yields. Their H-1 and C-13 NMR spectra were consistent with the structures depicted. These compounds quantitatively regenerate starting materials upon thermolysis.
ISSN:0300-922X
2050-8255
1364-5463
DOI:10.1039/p19940001433