Chirality makes a move

Interlocked molecules can exhibit chiral stereogenic elements that are not found in covalently bound systems. Now, the shuttling of the ring in a [2]rotaxane has been shown to result in enantiomeric co-conformations that selectively bind chiral guests.

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Bibliographic Details
Published inNature chemistry Vol. 11; no. 9; pp. 765 - 767
Main Authors Jamieson, Ellen M G, Goldup, Stephen M
Format Journal Article
LanguageEnglish
Published England Nature Publishing Group 01.09.2019
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Summary:Interlocked molecules can exhibit chiral stereogenic elements that are not found in covalently bound systems. Now, the shuttling of the ring in a [2]rotaxane has been shown to result in enantiomeric co-conformations that selectively bind chiral guests.
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ISSN:1755-4330
1755-4349
DOI:10.1038/s41557-019-0320-z