syn-BN-heteroacene cored conjugated oligomers with finely tuned blue-violet luminescent properties

Initiated by the effective dibromination of syn-BN-heteroacenes, a series of BN-containing conjugated oligomers was successfully synthesized upon transition-metal-catalyzed cross coupling. Their electronic structures can be finely tailored through varying the fused backbone or terminal substituents,...

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Published inOrganic & biomolecular chemistry Vol. 15; no. 34; pp. 7106 - 7111
Main Authors Zhang, Wanzheng, Fu, Yubin, Qiang, Peirong, Hunger, Jens, Bi, Shuai, Zhang, Wenbei, Zhang, Fan
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 30.08.2017
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
LIGHT-EMITTING-DIODES
POLYMERS
HETEROSUPERBENZENES
DESIGN
ACENES
FUSED N-HETEROACENE
AZABORINE COMPOUNDS
ORGANIC SEMICONDUCTORS
FIELD-EFFECT TRANSISTORS
ELECTRONICS
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Summary:Initiated by the effective dibromination of syn-BN-heteroacenes, a series of BN-containing conjugated oligomers was successfully synthesized upon transition-metal-catalyzed cross coupling. Their electronic structures can be finely tailored through varying the fused backbone or terminal substituents, endowing them with tunable luminescent properties within blue-violet regions.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
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ISSN:1477-0520
1477-0539
DOI:10.1039/c7ob01679d