Morphology and phase control of fluorides nanocrystals activated by lanthanides with two-model luminescence properties
The morphology, size and phase control of luminescent fluoride nanocrystals through doping has become a new research hotspot due to their improved properties. In this work, Yb(3+) ions, as one of the most efficient sensitizers for various lanthanide activators, were doped in NaGd(Y)F(4) nanocrystals...
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Published in | Nanoscale Vol. 4; no. 15; pp. 4658 - 4666 |
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Main Authors | , , , , , , |
Format | Journal Article |
Language | English |
Published |
England
07.08.2012
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Online Access | Get full text |
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Summary: | The morphology, size and phase control of luminescent fluoride nanocrystals through doping has become a new research hotspot due to their improved properties. In this work, Yb(3+) ions, as one of the most efficient sensitizers for various lanthanide activators, were doped in NaGd(Y)F(4) nanocrystals. The results show that no obvious influence was observed for Yb(3+)-doped NaYF(4) nanocrystals, while the influence of Yb(3+) doping on NaGdF(4) nanocrystals was remarkable. The NaGd(1-x)Yb(x)F(4) nanocrystals were synthesized by a hydrothermal route and had a morphology of rice-like nanorods. By controlling the synthesis parameters, the average size and slenderness of the nanocrystals increased gradually with addition of Yb(3+) ions. In contrast, the NaGd(1-x)Yb(x)F(4) nanocrystals maintained a hexagonal phase, which is more beneficial for application as a luminescent host, until the content of Yb(3+) ions reached x = 0.9. The growth and transformation mechanism of NaGd(1-x)Yb(x)F(4) nanocrystals was proposed to be a result of the competition between ion diffusion and an Oswald ripening process. Photoluminescence (PL) spectra confirm the efficient up-conversion and near-infrared (NIR) two-model luminescence properties of Er(3+) (Tm(3+)) activated NaGd(Y)(1-x)Yb(x)F(4) nanocrystals. Simulated analysis results indicate that a colloidal solution of mixed luminescent nanocrystals is expected to find application as the activated medium of three dimensional displays and a broadband optical amplifier. |
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Bibliography: | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
ISSN: | 2040-3364 2040-3372 |
DOI: | 10.1039/c2nr30998j |