Tuning ethylene gas adsorption via metal node modulation: Cu-MOF-74 for a high ethylene deliverable capacity

M-MOF-74s were examined for potential applications in ethylene abatement and/or storage/delivery. Due to labile binding resulting from a Jahn-Teller distortion, Cu-MOF-74 exhibits a gradual initial uptake that, in turn, translates into the highest deliverable capacity among the MOFs examined (3.6 mm...

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Published inChemical communications (Cambridge, England) Vol. 53; no. 67; pp. 9376 - 9379
Main Authors Liao, Yijun, Zhang, Lin, Weston, Mitchell H, Morris, William, Hupp, Joseph T, Farha, Omar K
Format Journal Article
LanguageEnglish
Published England 17.08.2017
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Summary:M-MOF-74s were examined for potential applications in ethylene abatement and/or storage/delivery. Due to labile binding resulting from a Jahn-Teller distortion, Cu-MOF-74 exhibits a gradual initial uptake that, in turn, translates into the highest deliverable capacity among the MOFs examined (3.6 mmol g ). In contrast, Co-MOF-74 is the most promising candidate for ethylene abatement due to the sharp uptake at low pressure.
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ISSN:1359-7345
1364-548X
DOI:10.1039/c7cc04160h