The synthesis of cycloalka[b]furans via an Au(I)-catalyzed tandem reaction of 3-yne-1,2-diols

An Au(I)-catalyzed cyclization/1,2-rearrangement/aromatization cascade of 3-yne-1,2-diols has been successfully realized. This reaction not only provides a new and efficient strategy for the synthesis of substituted cycloalka[b]furan compounds as well as their derivatives, but might also facilitate...

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Published inOrganic & biomolecular chemistry Vol. 15; no. 30; pp. 6333 - 6337
Main Authors Liu, Wei-Ting, Xu, Zheng-Liang, Mou, Xue-Qing, Zhang, Bang-Hong, Bao, Wen, Wang, Shao-Hua, Lee, Dongjun, Lei, Lin-Sheng, Zhang, Kun
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 02.08.2017
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
ELECTROPHILIC CYCLIZATION
MULTISUBSTITUTED FURANS
2-(1-ALKYNYL)-2-ALKEN-1-ONES
GOLD CATALYSIS
NATURAL-PRODUCTS
EFFICIENT SYNTHESIS
MODULAR ENTRY
BAND-GAP POLYMERS
HIGHLY SUBSTITUTED FURANS
CARBOXYLIC-ACIDS
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Summary:An Au(I)-catalyzed cyclization/1,2-rearrangement/aromatization cascade of 3-yne-1,2-diols has been successfully realized. This reaction not only provides a new and efficient strategy for the synthesis of substituted cycloalka[b]furan compounds as well as their derivatives, but might also facilitate related biological studies.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
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ISSN:1477-0520
1477-0539
DOI:10.1039/c7ob01179b