A self-catenated network containing unprecedented 0D + 2D → 2D polycatenation array

Herein, we report a new acylamide ligand and its application in the construction of a metal-organic framework. The resultant acylamide metal-organic framework, namely [Zn(2)(L)(OH)(btc)](n) (1, L = N(1),N(4)-bis(pyridin-3-ylmethyl) naphthalene-1,4-dicarboxamide, H(3)btc = benzene-1,3,5-tricarboxylic...

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Published inDalton transactions : an international journal of inorganic chemistry Vol. 41; no. 38; pp. 11559 - 11561
Main Authors Sun, Gong-ming, Luo, Feng, Song, Yu-mei, Tian, Xiao-zhao, Huang, Hai-xiao, Zhu, Yan, Yuan, Zi-jun, Feng, Xue-feng, Luo, Ming-biao, Liu, Shu-juan, Xu, Wen-yuan
Format Journal Article
LanguageEnglish
Published England 14.10.2012
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Summary:Herein, we report a new acylamide ligand and its application in the construction of a metal-organic framework. The resultant acylamide metal-organic framework, namely [Zn(2)(L)(OH)(btc)](n) (1, L = N(1),N(4)-bis(pyridin-3-ylmethyl) naphthalene-1,4-dicarboxamide, H(3)btc = benzene-1,3,5-tricarboxylic acid), was obtained by hydrothermal synthesis. The outstanding structural feature of it is the 0D + 2D → 2D polycatenation array containing a self-catenated feature which has never previously been observed. To the best of our knowledge, the coexistence of self-catenation and polycatenation phenomena is highly exceptional.
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ISSN:1477-9226
1477-9234
DOI:10.1039/c2dt31457f