Phase stability, piezoelectricity, and ferroelectricity in nitride short-period superlattices

• Published in: Journal of applied physics Vol. 136; no. 2
• Main Authors: Zhao, Ling-Xu, Liu, Jian
• Format: Journal Article
• Language: English
• Published: Melville American Institute of Physics 14.07.2024
• Subjects: Atomic structure; Ferroelectric materials; Ferroelectricity; Heterogeneity; Multilayers; Nitrides; Phase stability; Piezoelectricity; Structural stability; Superlattices; Wurtzite
• ISSN: 0021-8979; 1089-7550
• DOI: 10.1063/5.0214258

Improving piezoelectric and ferroelectric responses of group III-nitrides is desired for their potential applications in the emerging microelectromechanical-based systems. One possible approach to realize the optimization and control of functionalities is to bring together compounds with different properties to form the ordered multilayer superlattices. In this work, we systematically investigate the phase stability, piezoelectricity, and ferroelectricity in a class of wurtzite-structure-derived nitride superlattices with a periodic alternation of chemically and/or structurally different layers. The structural heterogeneity and phase stability of the ordered wurtzite-structure-derived superlattices are intimately related to the ionic radii mismatch between the substitutional compounds and the parent nitrides. Moreover, the internal structural distortion of the nitride superlattices has a crucial impact on the ferroelectricity and piezoelectricity, namely, piezoelectric and ferroelectric responses become increasingly enhanced as the buckled atomic layers becomes flatter. This work offers fundamental physical insights into the structure–property relationships in nitride superlattices and may propose some material design strategies for achieving high-performance materials with desired responses.