A facile approach to highly functional trisubstituted furans via intramolecular Wittig reactions
An efficient and mild synthesis of trisubstituted furans, starting from alpha,beta-unsaturated ketones, tributylphosphine, and acyl chlorides, is described. The strategy employs the intramolecular Wittig protocol as a key step to install the crucial furan ring, leading to a wide variety of highly fu...
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| Published in | Organic & biomolecular chemistry Vol. 9; no. 7; pp. 2098 - 2106 |
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| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
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CAMBRIDGE
Royal Soc Chemistry
07.04.2011
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| Subjects | |
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| Abstract | An efficient and mild synthesis of trisubstituted furans, starting from alpha,beta-unsaturated ketones, tributylphosphine, and acyl chlorides, is described. The strategy employs the intramolecular Wittig protocol as a key step to install the crucial furan ring, leading to a wide variety of highly functional furans in one step. |
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| AbstractList | An efficient and mild synthesis of trisubstituted furans, starting from alpha,beta-unsaturated ketones, tributylphosphine, and acyl chlorides, is described. The strategy employs the intramolecular Wittig protocol as a key step to install the crucial furan ring, leading to a wide variety of highly functional furans in one step. An efficient and mild synthesis of trisubstituted furans, starting from α,β-unsaturated ketones, tributylphosphine, and acyl chlorides, is described. The strategy employs the intramolecular Wittig protocol as a key step to install the crucial furan ring, leading to a wide variety of highly functional furans in one step.An efficient and mild synthesis of trisubstituted furans, starting from α,β-unsaturated ketones, tributylphosphine, and acyl chlorides, is described. The strategy employs the intramolecular Wittig protocol as a key step to install the crucial furan ring, leading to a wide variety of highly functional furans in one step. An efficient and mild synthesis of trisubstituted furans, starting from α,β-unsaturated ketones, tributylphosphine, and acyl chlorides, is described. The strategy employs the intramolecular Wittig protocol as a key step to install the crucial furan ring, leading to a wide variety of highly functional furans in one step. |
| Author | Chen, Ko-Wei Syu, Siang-en Jang, Yeong-Jiunn Lin, Wenwei |
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| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/21286654$$D View this record in MEDLINE/PubMed |
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| Keywords | NUCLEOPHILES 2-(1-ALKYNYL)-2-ALKEN-1-ONES HETEROCYCLES TETRASUBSTITUTED FURANS POLYSUBSTITUTED FURANS MODULAR ENTRY ALLENYL KETONES SUBSTITUTED FURANS CYCLIZATION REGIOCONTROLLED SYNTHESIS |
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| Snippet | An efficient and mild synthesis of trisubstituted furans, starting from alpha,beta-unsaturated ketones, tributylphosphine, and acyl chlorides, is described.... An efficient and mild synthesis of trisubstituted furans, starting from α,β-unsaturated ketones, tributylphosphine, and acyl chlorides, is described. The... |
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| Title | A facile approach to highly functional trisubstituted furans via intramolecular Wittig reactions |
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