Lithium Chloride-Assisted Chemoselective Conversion of Aldehydes into Geminal Diacetates Under Solvent-Free Conditions

A mixture of lithium chloride and acetic anhydride was used for converting aldehydes into geminal diacetates under solvent-free conditions in high yields.

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Bibliographic Details
Published inSynthetic communications Vol. 35; no. 10; pp. 1301 - 1305
Main Authors John Bosco, J. W., Purkayastha, N., Rama Raju, B., Saikia, Anil K.
Format Journal Article
LanguageEnglish
Published PHILADELPHIA Taylor & Francis Group 01.05.2005
Taylor & Francis
Subjects
Acetic anhydride
aldehydes
Chemistry
Chemistry, Organic
diacetylation
lithium chloride
Physical Sciences
Science & Technology
solvent-free
diacetylation
ACYLALS
lithium chloride
PROTECTION
ACETYLATION
acetic anhydride
solvent-free
AROMATIC-ALDEHYDES
CATALYST
DEPROTECTION
EFFICIENT METHOD
MILD
aldehydes
1,1-DIACETATES
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More Information
Summary:A mixture of lithium chloride and acetic anhydride was used for converting aldehydes into geminal diacetates under solvent-free conditions in high yields.
ISSN:0039-7911
1532-2432
DOI:10.1081/SCC-200057238