Transfer Hydrogenation of Aromatic Nitro Compounds Using Polymer-Supported Formate and Pd-C

Transfer hydrogenation of aromatic nitro compounds using recyclable polymer-supported formate as hydrogen donor and Pd-C as a catalyst produces corresponding amines in excellent yields (90-98%).

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Bibliographic Details
Published inSynthetic communications Vol. 35; no. 2; pp. 223 - 230
Main Authors Abiraj, K., Srinivasa, G. R., Gowda, D. Channe
Format Journal Article
LanguageEnglish
Published PHILADELPHIA Taylor & Francis Group 01.01.2005
Taylor & Francis
Subjects
10% Pd-C
amines
catalytic transfer hydrogenation
Chemistry
Chemistry, Organic
Nitro compounds
Physical Sciences
polymer-supported formate
Science & Technology
AMMONIUM FORMATE
amines
polymer-supported formate
TRIETHYLAMMONIUM FORMATE
SELECTIVE REDUCTION
AZO-COMPOUNDS
RANEY-NICKEL
N-BENZYL GROUPS
10% Pd-C
catalytic transfer hydrogenation
ARYL HALIDES
nitro compounds
PROTECTING GROUPS
PEPTIDE-SYNTHESIS
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Summary:Transfer hydrogenation of aromatic nitro compounds using recyclable polymer-supported formate as hydrogen donor and Pd-C as a catalyst produces corresponding amines in excellent yields (90-98%).
ISSN:0039-7911
1532-2432
DOI:10.1081/SCC-200048429