Orientation effects, hydrostatic response, and figures of merit in 2-2-type composites based on relaxor-ferroelectric single crystals

• Published in: Ferroelectrics Vol. 612; no. 1; pp. 56 - 67
• Main Authors: Topolov, V. Yu, Krivoruchko, A. V., Bowen, C. R., Isaeva, A. N., Prutsakova, N. V.
• Format: Journal Article
• Language: English
• Published: Philadelphia Taylor & Francis 18.08.2023; Taylor & Francis Ltd
• Subjects: Coupling; Crystallography; Crystals; domain-engineered single crystal; electromechanical coupling factor; Ferroelectric materials; Ferroelectricity; Figure of merit; hydrostatic parameters; Laminar composites; Parameters; Perovskite structure; Perovskites; Piezo-active composite; Piezoelectricity; Polymers; Porosity; Relaxors; Rotation; Single crystals; Specific volume
• ISSN: 0015-0193; 1563-5112
• DOI: 10.1080/00150193.2023.2211305

The article reports new results on the hydrostatic performance of laminar piezo-active composites based on domain-engineered relaxor-ferroelectric single crystals (SCs) with the perovskite-type structure. Layers of the composites are either single-crystal poled along [011] (where rotations of the main crystallographic axes around two co-ordinate axes are considered) or porous polymer, with aligned spheroidal pores. These composites are described by 2-2-0 connectivity. An influence of the rotation of the main crystallographic axes and porosity is analyzed, and maxima of the hydrostatic piezoelectric coefficient figure of merit and electromechanical coupling factor of the composites are found as functions of a few parameters. New diagrams are built to show regions of the large (over 1000 pC/N) at variations of two rotation angles in the single-crystal layers. Large values of the hydrostatic figure of merit  ∼ (10 −10 - 10 −9 ) Pa −1 and electromechanical coupling factor are achieved in specific volume-fraction and rotation-angle ranges. These and other large values of the hydrostatic parameters of the studied 2-2-type composites are important for effective hydroacoustic applications.