Highly efficient and expeditious PdO/SBA-15 catalysts for allylic oxidation of cyclohexene to cyclohexenone

A series of four PdO/SBA-15 catalysts with 1, 2, 4, 5% (by weight) loading of PdO have been prepared by a conventional impregnation method and are characterized by N 2 -adsorption, low-angle and wide-angle XRD, XPS and TEM techniques. The catalysts exhibited very high conversion of cyclohexene and h...

Full description

Saved in:
Bibliographic Details
Published inCatalysis science & technology Vol. 3; no. 2; pp. 49 - 414
Main Authors Ganji, Saidulu, Bukya, Padma, Vakati, Venkateswarlu, Rao, Kamaraju Seetha Rama, Burri, David Raju
Format Journal Article
LanguageEnglish
Published 01.01.2013
Subjects
Catalysis
Catalysts
Conversion
Cyclohexene
Impregnation
Selectivity
Transmission electron microscopy
X-ray photoelectron spectroscopy
Online AccessGet full text

Cover

More Information
Summary:A series of four PdO/SBA-15 catalysts with 1, 2, 4, 5% (by weight) loading of PdO have been prepared by a conventional impregnation method and are characterized by N 2 -adsorption, low-angle and wide-angle XRD, XPS and TEM techniques. The catalysts exhibited very high conversion of cyclohexene and high selectivity of cyclohexenone with 70% t -BuOOH in CH 3 CN. The structural and textural characteristics of catalysts play a crucial role in high conversion and selectivity. PdO/SBA-15 catalysts are prepared, which are highly effective for oxidation of cyclohexene into cyclohexenone with 100% conversion and 99% selectivity.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:2044-4753
2044-4761
DOI:10.1039/c2cy20627g