Methods for hydrosulfonylation of alkenes

Hydrofunctionalization is one of the most important transformation reactions of alkenes which allows for rapid increase in molecular complexity by installing functional groups across the carbon-carbon double bonds. In this context, over the past few years, the experimental synthesis of biologically...

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Bibliographic Details
Published inJournal of sulfur chemistry Vol. 45; no. 3; pp. 436 - 457
Main Authors Vessally, Esmail, Abdullah, Media Noori, Azeez, Maha Dhurgham, Poor Heravi, Mohammad Reza, Adil, Mohaned, Sami, Mustafa Humam, Adhab, Ayat Hussein
Format Journal Article
LanguageEnglish
Published Abingdon Taylor & Francis 03.05.2024
Taylor & Francis Ltd
Subjects
Alkenes
Carbon
Functional groups
hydrosulfonylation
Organosulfur chemistry
Sulfones
sulfonyl radical
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Summary:Hydrofunctionalization is one of the most important transformation reactions of alkenes which allows for rapid increase in molecular complexity by installing functional groups across the carbon-carbon double bonds. In this context, over the past few years, the experimental synthesis of biologically important aliphatic sulfones through the hydrosulfonylation of olefinic double bonds has attracted tremendous attention due to its straightforward manner with high atom- and step-economy, and also easily accessible starting materials. The aim of the present paper is to perform a review of recent advances made on this research topic, with special emphasis on the mechanistic aspect of the reactions.
ISSN:1741-5993
1741-6000
DOI:10.1080/17415993.2023.2278602