Synergy effects of Pr1.91Ni0.71Cu0.24Ga0.05O4 and Ba0.5La0.5CoO3 composite on cathodic activity for intermediate temperature solid oxide fuel cells

• Published in: Journal of power sources Vol. 228; pp. 229 - 236
• Main Authors: Xie, Jing, Ju, Young-Wan, Matsuka, Maki, Ida, Shitaro, Ishihara, Tatsumi
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier B.V 15.04.2013; Elsevier
• Subjects: Applied sciences; Cathode; Composite oxide; Direct energy conversion and energy accumulation; Electrical engineering. Electrical power engineering; Electrical power engineering; Electrical resistivity; Electrochemical conversion: primary and secondary batteries, fuel cells; Electrolytes; Energy; Energy. Thermal use of fuels; Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc; Exact sciences and technology; Fuel cells; Hole conductivity; La(Ba)CoO3; Materials; Maximum power density; Oxides; Pr2NiO4; Resistivity; Solid oxide fuel cell; Thin films; Three dimensional; Pr2NiO4; La(Ba)CoO3; Cathode; Solid oxide fuel cell; Composite oxide; Performance evaluation; Cobalt oxide; Power density; Oxygen; Pr; Electrical conductivity; Active site; Doped materials; La(Ba)CoO; Composite material; Overvoltage; Thin film; Lanthanum oxide; Three dimensional model; Electrolyte; NiO; Low k dielectric
• ISSN: 0378-7753; 1873-2755
• DOI: 10.1016/j.jpowsour.2012.11.089

Synergy effects of mixing Pr2NiO4 and La(Ba)CoO3 on cathodic performance were investigated using a LaGaO3-based oxide electrolyte. It was observed that cathodic overpotential could be suppressed significantly by mixing Pr2NiO4 with La(Ba)CoO3 base oxide, in spite of a decrease in the electrical conductivity. Because LaCoO3-doped with Ba shows high oxygen dissociation activity and Pr2NiO4 shows high oxide ion and hole conductivity, the active sites for oxygen dissociation could be extended in three dimensions. In response to the improved number of active sites, diffusion overpotential was decreased significantly by mixing Pr2NiO4-based oxide with LaCoO3-based oxide. The maximum power density of 117 mW cm−2 was achieved at temperatures as low as 673 K using a LaGaO3 thin film electrolyte (5-μm thick) and a composite oxide of Pr2NiO4–La(Ba)CoO3 cathode. ► Synergy effects of mixing Pr2NiO4 and La(Ba)CoO3 on cathodic performance were studied. ► Cathodic overpotential could be suppressed by mixing Pr2NiO4 with LaCoO3 base oxide. ► The active sites for oxygen dissociation could be extended in three dimensions. ► The maximum power density of 117 mW cm−2 was achieved at 673 K with this composite.