Dodecacarbonyltriruthenium catalyzed one-to-one addition of N-substituted formamide to olefins

Dodecacarbonyltriruthenium (Ru 3(CO) 12) showed high catalytic activity for the first one-to-one addition of N-substituted formamides to both terminal and internal olefins at 180-200°C under a carbon monoxide pressure of 20 kg cm −2. The addition of N-metylformamide to cyclopentene afforded N-methyl...

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Published inJournal of organometallic chemistry Vol. 331; no. 3; pp. 379 - 385
Main Authors Tsuji, Yasushi, Yoshii, Seiji, Ohsumi, Tatsuya, Kondo, Teruyuki, Watanabe, Yoshihisa
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.09.1987
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Summary:Dodecacarbonyltriruthenium (Ru 3(CO) 12) showed high catalytic activity for the first one-to-one addition of N-substituted formamides to both terminal and internal olefins at 180-200°C under a carbon monoxide pressure of 20 kg cm −2. The addition of N-metylformamide to cyclopentene afforded N-methylcyclopentanecarboxamide in 90% yield.
ISSN:0022-328X
1872-8561
DOI:10.1016/0022-328X(87)80009-8