Synthesis and physical properties of glasses in the Sb2O3―PbCl2―MoO3 system

• Published in: Journal of non-crystalline solids Vol. 357; no. 21; pp. 3572 - 3577
• Main Authors: GOUMEIDANE, F, LEGOUERA, M, IEZID, M, POULAIN, M, NAZABAL, V, LEBULLENGER, R
• Format: Journal Article
• Language: English
• Published: Oxford Elsevier 01.11.2011
• Subjects: Chemical Sciences; Condensed matter: structure, mechanical and thermal properties; Cross-disciplinary physics: materials science; rheology; Elasticity, elastic constants; Equations of state, phase equilibria, and phase transitions; Exact sciences and technology; Glass; Glass formation; Glass transitions; Glasses (including metallic glasses); Halides; Material chemistry; Materials science; Mechanical and acoustical properties of condensed matter; Mechanical properties of solids; Molybdates; Molybdenum trioxide; Oxides; Physical properties; Physics; Specific materials; Specific phase transitions; Synthesis; Elastic modulus; Phase transformations; Molar volume; Refractive index; Ternary systems; Crystallization; Glass; Molybdenum oxide; Oxychloride glass; Density; Microhardness; Antimony oxide; Physical properties; Glass formation; Glass transition; Thermal expansion; Chemical composition; Absorption spectra; Lead chloride
• ISSN: 0022-3093; 1873-4812
• DOI: 10.1016/j.jnoncrysol.2011.07.012

Lead chloroantimonite glasses form stable binary glasses that may accommodate numerous oxides or halides as a third component. Molybdenum trioxide is a glass progenitor leading to molybdate glasses. Ternary glasses have been synthesized and studied in the Sb2O3-PbCl2-MoO3system. Compositional limits of glass formation are reported and two series of glass samples have been prepared corresponding to the general formulas: (90-