A HIGHLY STEREOSELECTIVE SYNTHESIS OF ALPHA-GLUCOSIDES FROM 1-O-ACETYL GLUCOSE BY USE OF TIN(IV) CHLORIDE-SILVER PERCHLORATE CATALYST SYSTEM

In the presence of a catalytic amount of tin(IV) species generated from tin(IV) chloride and silver perchlorate, 1-O-acetyl-D-glucose stereoselectively reacts with silyl alkoxides to give the corresponding alpha-glucosides in high yields.

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Bibliographic Details
Published inChemistry letters no. 4; pp. 533 - 536
Main Authors MUKAIYAMA, T, TAKASHIMA, T, KATSURADA, M, AIZAWA, H
Format Journal Article
LanguageEnglish
Published TOKYO Chemical Soc Japan 01.04.1991
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
GLYCOSIDATION REACTION
GLUCOSYLATION
OLIGOSACCHARIDES
FLUORIDES
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Summary:In the presence of a catalytic amount of tin(IV) species generated from tin(IV) chloride and silver perchlorate, 1-O-acetyl-D-glucose stereoselectively reacts with silyl alkoxides to give the corresponding alpha-glucosides in high yields.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.1991.533