Facet-controlled phase separation in supersaturated Au-Ni nanoparticles upon shape equilibration

• Published in: Applied physics letters Vol. 107; no. 7
• Main Authors: Herz, A., Friák, M., Rossberg, D., Hentschel, M., Theska, F., Wang, D., Holec, D., Šob, M., Schneeweiss, O., Schaaf, P.
• Format: Journal Article
• Language: English
• Published: Melville American Institute of Physics 17.08.2015
• Subjects: ANISOTROPY; ANNEALING; Applied physics; Bilayers; CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS; CORRELATIONS; Drying; Elastic anisotropy; Elastic properties; EPITAXY; Gold; High temperature; Modulus of elasticity; NANOPARTICLES; Phase separation; PHYSICAL METALLURGY; QUANTUM MECHANICS; SOLID SOLUTIONS; SURFACES
• ISSN: 0003-6951; 1077-3118
• DOI: 10.1063/1.4928627

Solid-state dewetting is used to fabricate supersaturated, submicron-sized Au-Ni solid solution particles out of thin Au/Ni bilayers by means of a rapid thermal annealing technique. Phase separation in such particles is studied with respect to their equilibrium crystal (or Wulff) shape by subsequent annealing at elevated temperature. It is found that {100} faceting planes of the equilibrated particles are enriched with Ni and {111} faces with Au. Both phases are considered by quantum-mechanical calculations in combination with an error-reduction scheme that was developed to compensate for a missing exchange-correlation potential that would reliably describe both Au and Ni. The observed phase configuration is then related to the minimization of strongly anisotropic elastic energies of Au- and Ni-rich phases and results in a rather unique nanoparticle composite state that is characterized by nearly uniform value of elastic response to epitaxial strains all over the faceted surface. The same conclusion is yielded also by evaluating bi-axial elastic moduli when employing interpolated experimental elastic constants. This work demonstrates a useful route for studying features of physical metallurgy at the mesoscale.