First syntheses of 2-hydrogeno-2-oxo-1,4,2-oxazaphosphinanes via intramolecular esterification

Synthesis of 2-hydrogeno-2-oxo-1,4,2-oxazaphosphinanes via either intramolecular transesterification, using potassium tort-butylate as catalytic agent, or phosphinic acid esterification, is described for the first time. (C) 2003 Elsevier Science Ltd. All rights reserved.

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Bibliographic Details
Published inTetrahedron letters Vol. 44; no. 15; pp. 3183 - 3186
Main Authors Cristau, HJ, Monbrun, J, Tillard, M, Pirat, JL
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier 07.04.2003
Subjects
Chemical Sciences
Chemistry
Chemistry, Organic
Inorganic chemistry
Physical Sciences
Science & Technology
KETONES
intramolecular cyclization
ANALOGS
ACIDS
aminophosphinic acid
oxazaphosphinane
phosphorus heterocycles
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Summary:Synthesis of 2-hydrogeno-2-oxo-1,4,2-oxazaphosphinanes via either intramolecular transesterification, using potassium tort-butylate as catalytic agent, or phosphinic acid esterification, is described for the first time. (C) 2003 Elsevier Science Ltd. All rights reserved.
ISSN:0040-4039
1873-3581
DOI:10.1016/S0040-4039(03)00446-5