Photoinduced intramolecular electron transfer between fluorescein and carbazole

• Published in: Science China. Chemistry Vol. 40; no. 2; pp. 192 - 198
• Main Author: 张宏 张曼华 沈涛
• Format: Journal Article
• Language: English
• Published: Heidelberg Springer Nature B.V 01.04.1997
• Subjects: Absorption spectra; Carbazoles; carhazole; Duorescein; electron; Electron transfer; Emission analysis; Emission spectra; Fluorescein; Free energy; transfer
• ISSN: 1674-7291; 1006-9291; 1869-1870; 1862-2771
• DOI: 10.1007/BF02876411

Several dyads consisting of a fluoreseein covalently linked with a carhazole at site 2 or site 6 have been synthesized and characterized.Studies of absorption spectra,emission spectra and fluorescence lifetime quern hing Indicate that the ground-state interaction between fluorescein and carhazole in dyads is negligible and the intramolecular electron transfer (ET) reactions are mainly of dynamic process.Moreover,the efficiency and raie conslam of lectron transfer reactions in ZFO4 (carbazole linked at site 2’of fluorescein) are larg er than those in 4FOZ (carbazole linked at site 6 of fluorescein) 0 74; KET 11×108S-1),because the mutual orientation of donor and acceptor in ZFO4 is nearly face-to-face,which is more favorable to the process than the shoulder-to-shoulder mutual orientation in 4FOZ.Estimations are also formed of the free energy change of the photomduced electron transfer and the back reactions in the dyads.