Solid Supported Microwave-Assisted Beckmann Rearrangement of Ketoximes in Dry Media

An AlCl 3 -ZnCl 2 mixture supported on silica gel is found to be a new efficient medium for the Beckmann rearrangement in solvent-free conditions under microwave irradiation. The yields are good to excellent.

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Bibliographic Details
Published inSynthetic communications Vol. 34; no. 11; pp. 2071 - 2075
Main Authors Moghaddam, Firouz Matloubi, Rastegar Rad, Abbas Ali, Zali-Boinee, Hassan
Format Journal Article
LanguageEnglish
Published PHILADELPHIA Taylor & Francis Group 31.12.2004
Taylor & Francis
Subjects
Beckmann rearrangement
Chemistry
Chemistry, Organic
Ketoxime
Microwave irradiation
Physical Sciences
Science & Technology
Solid support
Solvent-free
microwave irradiation
solid support
solvent-free
Beckmann rearrangement
ketoxime
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Summary:An AlCl 3 -ZnCl 2 mixture supported on silica gel is found to be a new efficient medium for the Beckmann rearrangement in solvent-free conditions under microwave irradiation. The yields are good to excellent.
ISSN:0039-7911
1532-2432
DOI:10.1081/SCC-120037921