4-Amino-13-(1-naphthyl)-[2,2]paracyclophane

The title compound [systematic name: 12-amino-42-(1-naphthyl)-1,4(1,4)-dibenzenacyclohexaphane], C26H23N, was synthesized from 4-amino-13-bromo-[2,2]paracyclophane and 1-naphthaleneboronic acid in the presence of 1,4-dioxane. It is a new cyclophane-derived compound which can be regarded as a prospec...

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Bibliographic Details
Published inActa crystallographica. Section E, Structure reports online Vol. 64; no. 4; p. o650
Main Authors Sun, Junshan, Huo, Yanmin, Wu, Rentao, Li, Jikun, Ma, Yudao
Format Journal Article
LanguageEnglish
Published International Union of Crystallography 01.04.2008
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Summary:The title compound [systematic name: 12-amino-42-(1-naphthyl)-1,4(1,4)-dibenzenacyclohexaphane], C26H23N, was synthesized from 4-amino-13-bromo-[2,2]paracyclophane and 1-naphthaleneboronic acid in the presence of 1,4-dioxane. It is a new cyclophane-derived compound which can be regarded as a prospective ligand for asymmetric synthesis and catalysis. The benzene rings of the paracyclophane units are very slightly deformed from planarity as shallow boats.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536808005333